Ambulance staff will walk out on Wednesday - but life-threatening emergencies will be responded to.
The ambulance walkouts will involve paramedics as well as control room staff and support workers.
Speaking to BBC Radio Four's Today programme, Welsh Ambulance Service CEO Jason Killings said about 15% of callouts were for issues which were immediately life threatening, although this varied across the regions. Mr Barclay has said the government's pay award met the requirements of the recommendations of the independent NHS Pay Review Body and what was being asked for was "unaffordable".
He added: "But I'm keen to continue a dialogue with the trade unions because there's a range of issues that matter to staff," he said, referring to issues such as technology and safety.
Belgique Dernières Nouvelles, Belgique Actualités
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